Game crashing when starting new game

[MidbossVyers]

Uh... I think that this is a similar glitch to what killed my Oblivion game, but enough reminiscing. Anyway, after months of doing other things, I decided to get back into Skyrim. Upon doing so, I realized that everything was out of date, so after a couple days of updating and reinstalling stuff (yeah, thanks, NMM), everything looked good on paper. Because there were several mods that require complete reinstallation, instead of just updating, I figured that my old saves were now unusable, and I had them deleted. However, upon starting a new game, after a few seconds of Alduin on a word wall, my game crashed.

 

I know that one of reasons for games crashing on the Bethesda logo is because of missing masters. However, mine crashes on the initial loading screen. When loading up the game with SKSE, I got a message saying that TESVAL.dll is not designed to run on Windows or contains an error, but Skyrim still started up, so I paid it little mind. I have Fair Skin Complexion installed, so it might be that my computer cannot handle it, but I have since used Optimizer Textures to at least resize textures greater than 2048. This was usually enough. Still, this might even be a moot point because Fair Skin Complexion only affects females, and there are only male characters at the opening scene, such as Lokir, Ralof, and Ulfric (if one of the Legionnaires is female, then I wouldn't know). Here is my LOOT (I finally uninstalled BOSS for LOOT) load order and Papyrus log if they will help. Otherwise, I don't know of any better error trackers.

LOOT Order

0  0 Skyrim.esm

 1  1 Update.esm
 2  2 Unofficial Skyrim Patch.esp
 3  3 Dawnguard.esm
 4  4 Unofficial Dawnguard Patch.esp
 5  5 HearthFires.esm
 6  6 Unofficial Hearthfire Patch.esp
 7  7 Dragonborn.esm
 8  8 Unofficial Dragonborn Patch.esp
 9  9 Skyrim Project Optimization - Full Version.esm
10  a RaceCompatibility.esm
11  b MFVM.esm
12  c SexLab.esm
13  d Skykids.esm
14  e ZaZAnimationPack.esm
15  f Brawl Bugs CE.esp
16 10 Invisibility Eyes Fix.esp
17 11 RaceCompatibilityUSKPOverride.esp
18 12 MFVM_Hearthfire_Patch.esp
19 13 MFVM_ChildrenFight_Patch.esp
20 14 sanctuarycleanup.esp
21 15 ZazResources.esp
22 16 RaceMenu.esp
23 17 RaceMenuPlugin.esp
24 18 SkyUI.esp
25 19 Forsworn Boots Replacer.esp
26 1a FullMetalBikini.esp
27 1b Gatti12Jewelry.esp
28 1c LegendaryRings_Eng.esp
29 1d RealBarenziahV2Uncensored.esp
30 1e RV markers.esp
31 1f zzEstrus.esp
32 20 SK Vanilla Child Replacer.esp
33 21 SK Vanilla Child Replacer HF.esp
34 22 SK Vanilla Child Replacer DB.esp
35 23 StripNPCs.esp
36 24 Vampire Lord Serana Fixed.esp
37 25 CharGen ECE Morphs.esp
38 26 BarenziahQuestMarkers.esp
39 27 Babette Replacer.esp
40 28 RaceCompatibility-Dialog-Legendary.esp
41 29 SK Playable Kids Alt Male Body.esp

Papyrus log

Papyrus.0.log

[CGi]

The TESV Acceleration Layer SKSE plugin (TESVAL.dll) is highly outated and not needed anymore.
it's not only recommended to get rif of it, so please do that first and then try again.